KMID : 0370220090530050235
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Yakhak Hoeji 2009 Volume.53 No. 5 p.235 ~ p.240
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Optimum Concentration of the Cd(II)-Quercetin Complexation Reaction
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Lee Jeong-Ho
Shin Sun-Woo Baek Seung-Hwa
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Abstract
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The interaction of cadmium (II) ion with quercetin was investigated in aqueous solution at different pH. The quercetin/cadmium stochiometries for cadmium (II) binding have been determined by UV-vis spectrophotometric method. The complexation of Cd(II) ion with 54.72 µM quercetin (A = 1.00793) was formed in 0.2 M NH3-0.2 M NH4Cl (pH 8.0) buffer solution. 1 : 1 Cd(II)-complex had a maximum absorbance and showed the bathochromic shift of the long-wavelength band of the UV-vis spectra in the alkaline pH when interacted with quercetin in buffer solution. These results suggest that Cd(II)-quercetin complex has the optimal condition of chelation in basic buffer solution.
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KEYWORD
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quercetin, bathochromic shift, Cd(II)-complex, UV-vis spectrophotometric method
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